Zinedine Zidane is expected to take over as France's head coach after the 2026 FIFA World Cup, following the departure of Didier Deschamps after 14 years in charge.
This sets up Real Madrid final against Borussia Dortmund, who knocked out Paris Saint-Germain in the other semi-final.
Images from Sunday's action in LaLiga and Serie A.
Second-half strikes by Federico Valverde, Brahim Diaz and Endrick gave feeble Real Madrid an unconvincing 3-0 win over lowly Real Valladolid.
For Mourinho, it was an emotional night at the Estadio da Luz, capped by an extraordinary 98th-minute header from Trubin that ensured Benfica snatched a last-16 spot on goal difference.
Holders Manchester City cruised into the Champions League quarter-finals for the seventh consecutive season with a 3-1 victory over FC Copenhagen.
A summary of Saturday's action in the LaLiga, Serie A and Bundesliga.
Zinedine Zidane has stepped down as Real Madrid coach with immediate effect five days after his team were pipped to the La Liga title by city rivals Atletico Madrid, the Spanish club said on Thursday.
Real Madrid forward Vinicius Jr scored a hat-trick to help the LaLiga champions snap a two-game winless run in all competitions.
Federico Valverde scores a hat-trick as Real Madrid defeats Manchester City 3-0 in the first leg of their Champions League last-16 tie.
Champions Real Madrid earned a 2-0 win in a feisty LaLiga encounter at Athletic Bilbao on Sunday to ensure they stayed in the hunt for the LaLiga title with leaders Barcelona.
Real Madrid captain Sergio Ramos suggested after the Barcelona game that the players would not welcome him.
Former player and reserve team boss Santiago Solari has been put in caretaker charge after negotiations between the club and former Chelsea, Italy and Juventus boss Antonio Conte broke down on Monday, the club added.
Man City set to release skipper Gundogan and Mendy
Cristiano Ronaldo will call curtains on his illustrious career at Real Madrid, according to the Portuguese international's agent.
Real Madrid club doctors gave the all-clear to sign the 24-year-old player after a two and 3/4-hour medical.
Rafa Benitez has been sacked as coach of Real Madrid, according to reports in the Spanish press. Sunday night's 2-2 draw with Valencia has proved to be the final straw for president Florentino Perez with the club likely to confirm the news soon. France legend Zinedine Zidane - the coach of Real Madrid's second team, Castilla - is expected to take over.
Real Madrid will join the complaint filed on Friday by Spanish prosecutors against Barcelona and two of the LaLiga club's ex-presidents over alleged payments to a company owned by a senior refereeing official to influence match results.
Gareth Bale has reiterated his plan to return to Real Madrid once his loan spell at Tottenham Hotspur is over and played down suggestions his comments were disrespectful to the London club.
The 31-year-old will leave Real Madrid at the end of the season and sign a five-year deal for MLS side Los Angeles Galaxy.
Several high-profile football players are facing injuries ahead of the World Cup, raising concerns about their participation in the tournament. Kylian Mbappe, Lamine Yamal, and other stars are among those sidelined, while the packed playing schedule is drawing criticism.
Zinedine Zidane said he would be willing to become Real Madrid head coach although he is not in a hurry.
Zidane was accompanied on stage by his wife and four sons, who all look good to follow in the footsteps of their father.
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Zidane is currently in charge of Real's B team Castilla, and has for some time been linked with the manager's post.
'Messi's departure is a move that helps Florentino. Imagine that (Kylian) Mbappe now signs for Real Madrid.'
Barcelona missed the chance to reclaim the LaLiga summit after suffering a 2-1 derby defeat to Girona, who roared back in the second half to leave Real Madrid top of the table.
Uruguayan midfielder Fabian Canobbio scored a contentious goal to give promoted Celta Vigo a 3-2 win.
Zinedine Zidane is the right man for the job of Real Madrid coach, former team-mate David Beckham said on Monday after the Spanish club sacked Rafa Benitez and replaced him with the French World Cup winner. "Does it get any better than this??," the former England captain, who played with Zidane at Real after joining from Manchester United in 2003, declared on Instagram.
Blackburn Rovers have signed former Real Madrid defender Michel Salgado for two years on a free transfer, the Premier League club said on Wednesday.
Real Madrid suffered a shock 1-0 home defeat to Real Betis on Wednesday as an inspired performance from their former goalkeeper Antonio Adan and a stoppage-time winner from Antonio Sanabria stunned the Liga champions.
Zinedine Zidane can stay at Real Madrid for life, club President Florentino Perez said on Saturday, after the Frenchman became the first manager to win the Champions League two years in a row with a dominant 4-1 win over Juventus.
Holders Real Madrid will play 2021 winners Chelsea in the Champions League quarter-finals while Manchester City's Pep Guardiola will visit his former club Bayern Munich.
Real Madrid agreed to sign experienced Portugal defender Ricardo Carvalho from Chelsea on a two-year contract on Tuesday.
Former Real Madrid soccer star Alfredo Di Stefano, 88, has died in a Madrid hospital two days after suffering a heart attack, Spanish newspapers reported on Monday.
Former France soccer great Raymond Kopa, who won three European Cups with Real Madrid in the 1950s, died at the age of 85 on Friday.
Real Madrid's sporting director Predrag Mijatovic was quoted As saying that the England captain will not be offered a new contract and leave the club.